Radiometric dating - Wikipedia
Dating Techniques - Stratigraphy, Seriation, Faunal Dating, Pollen Dating ( palynology), Amino Acid Racimization, Cation-ratio Dating - Relative dating, Absolute. Radiometric dating or radioactive dating is a technique used to date materials such as rocks or Together with stratigraphic principles, radiometric dating methods are used in geochronology to establish the geologic time scale. Among the. Radiometric dating is used to estimate the age of rocks and other objects based on the fixed decay rate of radioactive isotopes. Learn about.
The recognition of the utility of fossils for more precise "relative dating" is often attributed to William Smith, a canal engineer who observed the fossil succession while digging through the rocks of southern England. But scientists like Albert Oppel hit upon the same principles at about about the same time or earlier.
In Smith's case, by using empirical observations of the fossil succession, he was able to propose a fine subdivision of the rocks and map out the formations of southern England in one of the earliest geological maps Other workers in the rest of Europe, and eventually the rest of the world, were able to compare directly to the same fossil succession in their areas, even when the rock types themselves varied at finer scale.
For example, everywhere in the world, trilobites were found lower in the stratigraphy than marine reptiles. Dinosaurs were found after the first occurrence of land plants, insects, and amphibians. Spore-bearing land plants like ferns were always found before the occurrence of flowering plants. The observation that fossils occur in a consistent succession is known as the "principle of faunal and floral succession".
The study of the succession of fossils and its application to relative dating is known as "biostratigraphy". Each increment of time in the stratigraphy could be characterized by a particular assemblage of fossil organisms, formally termed a biostratigraphic "zone" by the German paleontologists Friedrich Quenstedt and Albert Oppel. These zones could then be traced over large regions, and eventually globally.
Groups of zones were used to establish larger intervals of stratigraphy, known as geologic "stages" and geologic "systems". The time corresponding to most of these intervals of rock became known as geologic "ages" and "periods", respectively. By the end of the s, most of the presently-used geologic periods had been established based on their fossil content and their observed relative position in the stratigraphy e.
These terms were preceded by decades by other terms for various geologic subdivisions, and although there was subsequent debate over their exact boundaries e. By the s, fossil succession had been studied to an increasing degree, such that the broad history of life on Earth was well understood, regardless of the debate over the names applied to portions of it, and where exactly to make the divisions.
All paleontologists recognized unmistakable trends in morphology through time in the succession of fossil organisms.
- Radiometric Dating and the Geological Time Scale
This observation led to attempts to explain the fossil succession by various mechanisms. Perhaps the best known example is Darwin's theory of evolution by natural selection. Note that chronologically, fossil succession was well and independently established long before Darwin's evolutionary theory was proposed in Fossil succession and the geologic time scale are constrained by the observed order of the stratigraphy -- basically geometry -- not by evolutionary theory.
Calibrating the Relative Time Scale For almost the next years, geologists operated using relative dating methods, both using the basic principles of geology and fossil succession biostratigraphy. Various attempts were made as far back as the s to scientifically estimate the age of the Earth, and, later, to use this to calibrate the relative time scale to numeric values refer to "Changing views of the history of the Earth" by Richard Harter and Chris Stassen.
Most of the early attempts were based on rates of deposition, erosion, and other geological processes, which yielded uncertain time estimates, but which clearly indicated Earth history was at least million or more years old. A challenge to this interpretation came in the form of Lord Kelvin's William Thomson's calculations of the heat flow from the Earth, and the implication this had for the age -- rather than hundreds of millions of years, the Earth could be as young as tens of million of years old.
This evaluation was subsequently invalidated by the discovery of radioactivity in the last years of the 19th century, which was an unaccounted for source of heat in Kelvin's original calculations. With it factored in, the Earth could be vastly older. Estimates of the age of the Earth again returned to the prior methods.
Evolution -- Dating Methods
The discovery of radioactivity also had another side effect, although it was several more decades before its additional significance to geology became apparent and the techniques became refined. Because of the chemistry of rocks, it was possible to calculate how much radioactive decay had occurred since an appropriate mineral had formed, and how much time had therefore expired, by looking at the ratio between the original radioactive isotope and its product, if the decay rate was known.
Many geological complications and measurement difficulties existed, but initial attempts at the method clearly demonstrated that the Earth was very old. In fact, the numbers that became available were significantly older than even some geologists were expecting -- rather than hundreds of millions of years, which was the minimum age expected, the Earth's history was clearly at least billions of years long.
Radiometric dating provides numerical values for the age of an appropriate rock, usually expressed in millions of years. Therefore, by dating a series of rocks in a vertical succession of strata previously recognized with basic geologic principles see Stratigraphic principles and relative timeit can provide a numerical calibration for what would otherwise be only an ordering of events -- i.
The integration of relative dating and radiometric dating has resulted in a series of increasingly precise "absolute" i. Given the background above, the information used for a geologic time scale can be related like this: How relative dating of events and radiometric numeric dates are combined to produce a calibrated geological time scale. In this example, the data demonstrates that "fossil B time" was somewhere between and million years ago, and that "fossil A time" is older than million years ago.
Note that because of the position of the dated beds, there is room for improvement in the time constraints on these fossil-bearing intervals e. A continuous vertical stratigraphic section will provide the order of occurrence of events column 1 of Figure 2. These are summarized in terms of a "relative time scale" column 2 of Figure 2. Geologists can refer to intervals of time as being "pre-first appearance of species A" or "during the existence of species A", or "after volcanic eruption 1" at least six subdivisions are possible in the example in Figure 2.
For this type of "relative dating" to work it must be known that the succession of events is unique or at least that duplicate events are recognized -- e. Unique events can be biological e. Ideally, geologists are looking for events that are unmistakably unique, in a consistent order, and of global extent in order to construct a geological time scale with global significance.
Some of these events do exist. For example, the boundary between the Cretaceous and Tertiary periods is recognized on the basis of the extinction of a large number of organisms globally including ammonites, dinosaurs, and othersthe first appearance of new types of organisms, the presence of geochemical anomalies notably iridiumand unusual types of minerals related to meteorite impact processes impact spherules and shocked quartz.
These types of distinctive events provide confirmation that the Earth's stratigraphy is genuinely successional on a global scale. Even without that knowledge, it is still possible to construct local geologic time scales. Although the idea that unique physical and biotic events are synchronous might sound like an "assumption", it is not. It can, and has been, tested in innumerable ways since the 19th century, in some cases by physically tracing distinct units laterally for hundreds or thousands of kilometres and looking very carefully to see if the order of events changes.
Geologists do sometimes find events that are "diachronous" i. Because any newly-studied locality will have independent fossil, superpositional, or radiometric data that have not yet been incorporated into the global geological time scale, all data types serve as both an independent test of each other on a local scaleand of the global geological time scale itself.
The test is more than just a "right" or "wrong" assessment, because there is a certain level of uncertainty in all age determinations. For example, an inconsistency may indicate that a particular geological boundary occurred 76 million years ago, rather than 75 million years ago, which might be cause for revising the age estimate, but does not make the original estimate flagrantly "wrong".
It depends upon the exact situation, and how much data are present to test hypotheses e. Whatever the situation, the current global geological time scale makes predictions about relationships between relative and absolute age-dating at a local scale, and the input of new data means the global geologic time scale is continually refined and is known with increasing precision.
This trend can be seen by looking at the history of proposed geologic time scales described in the first chapter of [Harland et al,p. The unfortunate part of the natural process of refinement of time scales is the appearance of circularity if people do not look at the source of the data carefully enough. Most commonly, this is characterised by oversimplified statements like: When a geologist collects a rock sample for radiometric age dating, or collects a fossil, there are independent constraints on the relative and numerical age of the resulting data.
Stratigraphic position is an obvious one, but there are many others. There is no way for a geologist to choose what numerical value a radiometric date will yield, or what position a fossil will be found at in a stratigraphic section.
Every piece of data collected like this is an independent check of what has been previously studied. The data are determined by the rocks, not by preconceived notions about what will be found. Every time a rock is picked up it is a test of the predictions made by the current understanding of the geological time scale. The time scale is refined to reflect the relatively few and progressively smaller inconsistencies that are found.
This is not circularity, it is the normal scientific process of refining one's understanding with new data. It happens in all sciences. If an inconsistent data point is found, geologists ask the question: However, this statistical likelihood is not assumed, it is tested, usually by using other methods e. Geologists search for an explanation of the inconsistency, and will not arbitrarily decide that, "because it conflicts, the data must be wrong. The continued revision of the time scale as a result of new data demonstrates that geologists are willing to question it and change it.
The geological time scale is far from dogma. If the new data have a large inconsistency by "large" I mean orders of magnitudeit is far more likely to be a problem with the new data, but geologists are not satisfied until a specific geological explanation is found and tested.
An inconsistency often means something geologically interesting is happening, and there is always a tiny possibility that it could be the tip of a revolution in understanding about geological history. Admittedly, this latter possibility is VERY unlikely. There is almost zero chance that the broad understanding of geological history e. The amount of data supporting that interpretation is immense, is derived from many fields and methods not only radiometric datingand a discovery would have to be found that invalidated practically all previous data in order for the interpretation to change greatly.
So far, I know of no valid theory that explains how this could occur, let alone evidence in support of such a theory, although there have been highly fallacious attempts e. When Radiometric Dating "Just Works" or not A poor example There are many situations where radiometric dating is not possible, or where a dating attempt will be fraught with difficulty.
This is the inevitable nature of rocks that have experienced millions of years of history: The real question is what happens when conditions are ideal, versus when they are marginal, because ideal samples should give the most reliable dates. If there are good reasons to expect problems with a sample, it is hardly surprising if there are! It contains a mixture of minerals from a volcanic eruption and detrital mineral grains eroded from other, older rocks. If the age of this unit were not so crucial to important associated hominid fossils, it probably would not have been dated at all because of the potential problems.
After some initial and prolonged troubles over many years, the bed was eventually dated successfully by careful sample preparation that eliminated the detrital minerals. Lubenow's work is fairly unique in characterising the normal scientific process of refining a difficult date as an arbitrary and inappropriate "game", and documenting the history of the process in some detail, as if such problems were typical.
Geochronology - Wikipedia
Another example is "John Woodmorappe's" paper on radiometric datingwhich adopts a "compilation" approach, and gives only superficial treatment to the individual dates. Among other problems documented in an FAQ by Steven Schimmrichmany of Woodmorappe's examples neglect the geological complexities that are expected to cause problems for some radiometrically-dated samples. A good example By contrast, the example presented here is a geologically simple situation -- it consists of several primary i.
It demonstrates how consistent radiometric data can be when the rocks are more suitable for dating. For most geological samples like this, radiometric dating "just works". Consider this stratigraphic section from the Bearpaw Formation of Saskatchewan, Canada Baadsgaard et al.
Modified from Baadsgaard et al. The section is measured in metres, starting with 0m at the bottom oldest. This section is important because it places a limit on the youngest age for a specific ammonite shell -- Baculites reesidei -- which is used as a zonal fossil in western North America.
It consistently occurs below the first occurrence of Bacultes jenseni and above the occurrence of Baculites cuneatus within the upper part of the Campanian, the second to last "stage" of the Cretaceous Period in the global geological time scale.
The biostratigraphic situation can be summarized as a vertically-stacked sequence of "zones" defined by the first appearance of each ammonite species: About 40 of these ammonite zones are used to subdivide the upper part of the Cretaceous Period in this area. Dinosaurs and many other types of fossils are also found in this interval, and in broad context it occurs shortly before the extinction of the dinosaurs, and the extinction of all ammonites.
The Bearpaw Formation is a marine unit that occurs over much of Alberta and Saskatchewan, and it continues into Montana and North Dakota in the United States, although it adopts a different name in the U. The numbers above are just summary values.
Other examples yield similar results - i. The results are therefore highly consistent given the analytical uncertainties in any measurement. Eberth and Braman described the vertebrate paleontology and sedimentology of the Judith River Formation, a dinosaur-bearing unit that occurs stratigraphically below the Baculites reesidei zone the Judith River Formation is below the Bearpaw Formation.
It should therefore be older than the results from Baadsgaard et al. An ash bed near the top of the Judith River Fm. Again, this is compatible with the age determined for the Baculites reesidei zone and its relative stratigraphic position, and even with the relative position of the two samples within the same formation. How do these dates compare to the then current geological time scale? Here are the numbers they applied to the geological boundaries in this interval, compared to the numbers in the newer studies: Comparison of newer data with the Harland et al.
As you can see, the numbers in the rightmost column are basically compatible. Skeptics of radiometric dating procedures sometimes claim these techniques should not work reliably, or only infrequently, but clearly the results are similar: The possible confounding effects of contamination of parent and daughter isotopes have to be considered, as do the effects of any loss or gain of such isotopes since the sample was created.
It is therefore essential to have as much information as possible about the material being dated and to check for possible signs of alteration.
Alternatively, if several different minerals can be dated from the same sample and are assumed to be formed by the same event and were in equilibrium with the reservoir when they formed, they should form an isochron. This can reduce the problem of contamination. In uranium—lead datingthe concordia diagram is used which also decreases the problem of nuclide loss. Finally, correlation between different isotopic dating methods may be required to confirm the age of a sample.
For example, the age of the Amitsoq gneisses from western Greenland was determined to be 3. The procedures used to isolate and analyze the parent and daughter nuclides must be precise and accurate. This normally involves isotope-ratio mass spectrometry. For instance, carbon has a half-life of 5, years.
After an organism has been dead for 60, years, so little carbon is left that accurate dating cannot be established. On the other hand, the concentration of carbon falls off so steeply that the age of relatively young remains can be determined precisely to within a few decades. Closure temperature If a material that selectively rejects the daughter nuclide is heated, any daughter nuclides that have been accumulated over time will be lost through diffusionsetting the isotopic "clock" to zero.
The temperature at which this happens is known as the closure temperature or blocking temperature and is specific to a particular material and isotopic system. These temperatures are experimentally determined in the lab by artificially resetting sample minerals using a high-temperature furnace.
As the mineral cools, the crystal structure begins to form and diffusion of isotopes is less easy. At a certain temperature, the crystal structure has formed sufficiently to prevent diffusion of isotopes. This temperature is what is known as closure temperature and represents the temperature below which the mineral is a closed system to isotopes. Thus an igneous or metamorphic rock or melt, which is slowly cooling, does not begin to exhibit measurable radioactive decay until it cools below the closure temperature.
The age that can be calculated by radiometric dating is thus the time at which the rock or mineral cooled to closure temperature. This field is known as thermochronology or thermochronometry. The age is calculated from the slope of the isochron line and the original composition from the intercept of the isochron with the y-axis. The equation is most conveniently expressed in terms of the measured quantity N t rather than the constant initial value No.
The above equation makes use of information on the composition of parent and daughter isotopes at the time the material being tested cooled below its closure temperature. This is well-established for most isotopic systems. Plotting an isochron is used to solve the age equation graphically and calculate the age of the sample and the original composition.
Modern dating methods[ edit ] Radiometric dating has been carried out since when it was invented by Ernest Rutherford as a method by which one might determine the age of the Earth. In the century since then the techniques have been greatly improved and expanded.
The mass spectrometer was invented in the s and began to be used in radiometric dating in the s. It operates by generating a beam of ionized atoms from the sample under test. The ions then travel through a magnetic field, which diverts them into different sampling sensors, known as " Faraday cups ", depending on their mass and level of ionization. On impact in the cups, the ions set up a very weak current that can be measured to determine the rate of impacts and the relative concentrations of different atoms in the beams.
Uranium—lead dating method[ edit ] Main article: Uranium—lead dating A concordia diagram as used in uranium—lead datingwith data from the Pfunze BeltZimbabwe. This scheme has been refined to the point that the error margin in dates of rocks can be as low as less than two million years in two-and-a-half billion years.
Zircon has a very high closure temperature, is resistant to mechanical weathering and is very chemically inert. Zircon also forms multiple crystal layers during metamorphic events, which each may record an isotopic age of the event. This can be seen in the concordia diagram, where the samples plot along an errorchron straight line which intersects the concordia curve at the age of the sample.
Samarium—neodymium dating method[ edit ] Main article: Samarium—neodymium dating This involves the alpha decay of Sm to Nd with a half-life of 1. Accuracy levels of within twenty million years in ages of two-and-a-half billion years are achievable. Potassium—argon dating This involves electron capture or positron decay of potassium to argon Potassium has a half-life of 1.
Rubidium—strontium dating method[ edit ] Main article: Rubidium—strontium dating This is based on the beta decay of rubidium to strontiumwith a half-life of 50 billion years. This scheme is used to date old igneous and metamorphic rocksand has also been used to date lunar samples. Closure temperatures are so high that they are not a concern. Rubidium-strontium dating is not as precise as the uranium-lead method, with errors of 30 to 50 million years for a 3-billion-year-old sample.
Uranium—thorium dating method[ edit ] Main article: Uranium—thorium dating A relatively short-range dating technique is based on the decay of uranium into thorium, a substance with a half-life of about 80, years. It is accompanied by a sister process, in which uranium decays into protactinium, which has a half-life of 32, years. While uranium is water-soluble, thorium and protactinium are not, and so they are selectively precipitated into ocean-floor sedimentsfrom which their ratios are measured.
The scheme has a range of several hundred thousand years. A related method is ionium—thorium datingwhich measures the ratio of ionium thorium to thorium in ocean sediment.